ELECTROCHEMICAL BEHAVIOUR OF AISI 304 STAINLESS STEEL IN SULFURIC SOLUTION: EFFECTS OF ACID CONCENTRATION
Authors
Abstract:
The effects of H2SO4 concentration on the electrochemical behaviour of passive films formed on AISI 304 stainless steel were investigated using by potentiodynamic polarization, Mott–Schottky analysis and electrochemical impedance spectroscopy (EIS). Potentiodynamic polarization indicated that the corrosion potentials were found to shift towards negative direction with an increase in solution concentration. Also, the corrosion current densities increase with an increase in solution concentration. Mott–Schottky analysis revealed that the passive films behave as n-type and p-type semiconductors at potentials below and above the flat band potential, respectively. Also, Mott– Schottky analysis indicated that the donor and acceptor densities are in the range 1021 cm-3 and increased with solution concentration. EIS data showed that the equivalent circuit Rs(Qdl[Rct(RrQr)]) by two time constants is applicable.
similar resources
The Effect of Solution Concentration on the Electrochemical Behaviour of AISI 321 Stainless Steel in Sulfuric Solutions
full text
the effect of solution concentration on the electrochemical behaviour of aisi 321 stainless steel in sulfuric solutions
full text
EFFECT OF IMMERSION TIME ON THE ELECTROCHEMICAL BEHAVIOUR OF AISI 321 STAINLESS STEEL IN 0.1 M H2SO4 SOLUTION
In this study, effect of immersion time on the electrochemical behaviour of AISI 321 stainless steel (AISI 321) in 0.1 M H 2SO 4 solution under open circuit potential (OCP) conditions was evaluated by potentiodynamic polarization, Mott–Schottky analysis and electrochemical impedance spectroscopy (EIS). Mott–Schottky analysis revealed that the passive films behave as n-type and p-type s...
full textDetermination of susceptibility to intergranular corrosion and electrochemical reactivation behaviour of AISI 316L type stainless steel
In this study, double loop electrochemical potentiokinetic reactivation (DLEPR) test was applied to determine the degree of sensitization in 316L type stainless steel, where obtained results were correlated with revealed microstructures after oxalic acid test and weight loss measurements of Streicher and Huey acid tests. Best agreement was provided with test parameters which are 1 M H2SO4 and 0...
full textCompressibility of 304 Stainless Steel Powder Metallurgy Materials Reinforced with 304 Short Stainless Steel Fibers
Powder metallurgy (P/M) technique is usually used for manufacturing porous metal materials. However, some P/M materials are limitedly used in engineering for their performance deficiency. A novel 304 stainless steel P/M material was produced by a solid-state sintering of 304 stainless steel powders and 304 short stainless steel fibers, which were alternately laid in layers according to mass rat...
full textA Comparative Study of Corrosive-Erosive Effects at AISI D3 Steel, 304 Stainless Steel and CrN/AlN Material
Corrosive-erosive effect on AISI D3 steel, 304 stainless steel and CrN/AlN coating in aqueous NaCl slurries was studied. CrN/AlN multilayer films with a thickness of 3 m and bilayer period of = 60 nm (50 bilayers) were obtained by using the physical vapor deposition (PVD) technique (magnetron sputtering). The corrosion-erosion experiments were performed in a test machine in which the impingemen...
full textMy Resources
Journal title
volume 10 issue 4
pages 31- 42
publication date 2013-12
By following a journal you will be notified via email when a new issue of this journal is published.
Hosted on Doprax cloud platform doprax.com
copyright © 2015-2023